1673-159X

CN 51-1686/N

基于可瓷化填料的玄武岩纤维增强硼酚醛树脂复合材料高温性能研究

Research on the High-temperature Performance of the Basalt Fiber Reinforced Boron Phenolic Resin Composite Based on Ceramifiable Fillers

  • 摘要: 为提高玄武岩纤维复合材料的耐高温性能,通过预浸料模压工艺制备基于可瓷化填料的玄武岩纤维增强硼酚醛树脂复合材料,采用TG测试、DMA测试、高温力学测试、扫描电镜等方法测试复合材料的热稳定性、动态力学性能、高温力学性能。结果表明:随着可瓷化填料含量的增加,复合材料的耐高温性能显著提升;可瓷化填料添加量50%相较未添加材料的热失重5%对应的温度T5%提升了41 ℃,分解峰温度Tmax提升了12 ℃; 1 000 ℃下的残炭率为77.6%,提高了19.0%;常温下随着填料含量的增加,复合材料弯曲强度表现出先增后减的变化趋势,300、400、600 ℃处理后添加量为40%时达最大值,弯曲强度分别为356、217、68.2 MPa,强度保留率分别为89.2%、54.4%、17.1%;复合材料储能模量表现出先增后减的变化趋势,玻璃化转变温度Tg随可瓷化填料含量的增加而升高,相较未添加可瓷化填料复合材料,添加量为50%时,Tg提高49 ℃。

     

    Abstract: To improve the high-temperature resilience of basalt fiber composite materials, this study utilized the prepreg molding technique to manufacture basalt fiber-reinforced boron-phenolic resin composites incorporating ceramicizable fillers. The thermal stability, dynamic mechanical properties, and high-temperature mechanical performance of the composites were evaluated through TG testing, DMA analysis, high-temperature mechanical testing, and scanning electron microscopy. The outcomes indicate a substantial enhancement in the high-temperature resistance of the composite materials with an increase in ceramicizable filler content. Specifically, at 50% filler content, the temperature corresponding to 5% weight loss (T5% )of the composite material rises by 41°C, while peak decomposition temperature(Tmax) increases by 12°C compared to the filler-free composite. Furthermore, the carbon residue rate at 1000°C escalates by 19.0%, reaching 77.6%. At room temperature, as the content of the filler increases, the bending strength of the composite material shows a trend of increasing first and then decreasing. After being treated at 300, 400, and 600℃, when the addition amount is 40%, the maximum value is reached, and the bending strengths are 356, 217, and 68.2 MPa respectively, with the strength retention rates being 89.2%, 54.4%, and 17.1% respectively. DMA analysis unveiled a trend in the storage modulus of the composite material, showing an initial increase followed by a decrease. Concurrently, the glass transition temperature (Tg) rises with the incorporation of ceramicizable fillers. Specifically, at a 50% filler addition, the Tg temperature escalates by 49°C compared to the composite lacking ceramicizable fillers.

     

/

返回文章
返回